أستمارة بيانات عضو هيئة تدريس

Name: Fatma S. M. Hassan

Faculty of Science at Aswan

Department: Chemistry

Telephone (Home): (079)2317279

Mobile: 0106089564

Fax: (097)3480450

E-mail: fatma_smh@yahoo.com

Major Research Field: Inorganic Chemistry

Specific Research Field: Organometallic Compounds.

M.Sc. Title: Physico-Chemical Studies on Vanadium, Niobium and Tautalum complexes.

Ph.D. Title: New coordination Chemistry with Bis(dipheiylphesphino) methane or 1.1- bis(dipheiyl sphine).

Important Publication that Represent Your Scientific Activities:

1. Bimetallic Systems. Part 7. Platinum and palladium dicyanides containing terminal or bridging Ph2PCH2PPh2 and heterometallics with silver, gold, mercury, rhodium, iridium or molybdenum.

Fatma .S.M.Hassan, David P. Markham, Paul G. Pringle, and Bernard L.Shaw. J .Chem. , Soc. ,Dalton Trans. ,1985 ,279.

2. Synthetic and nuclear magnetic resonance studies on dialkyl -or -diaryl- platinum complexes containing chelating monodentate , or bridging Ph2PCH2PPh2( dppm ) Ligands .

Fatma .S.M .Hassan ,David M McEwan, Paul G. Pringle , and Bernard L. Shaw

J .Chem. ,Soc. ,Dalton Trans.1985, 1501.

3. Novel routs to functionalized diphosphine- M(CO) complexes (M= W,Mo,Cr). Gary Cooper, Fatma .S.M .Hassan , Bernard L. Shaw ,and M. Thoronton-Pett, J.Chem., Soc., Chem. Commun. ,1985,615.

4. Very high activity of ( Ph2P)2=CH2 to Michael additions when complexes to platinum(II) or platinum(IV) .

X.L. Fontaine , F.S.M. Hassan , S.J.Higgins , G.B.Jacobsen , B.L.Shaw, and M.Thoronton-Pett. J.Chem., Soc., Chem. Commun. , 1985, 1635.

5. Conjugate addition of acetylides to complexes of type [M (OC)4 { (Ph2P)2C=CH2} ] (M= Cr,Mo, or W ). Crystal structure of [M (OC) 4 { (Ph2P) C=CHCH=CHPh } ]. Formed by the base catalysed isomerisation of [ M (OC)4 { (phzP)zCHCHzC=CPh }].

Fatma .S.M .Hassan ,Bernard L. Shaw and M. Thoronton-Pett,

J .Chem. ,Soc. ,Dalton Trans. 1988,89.

6. Nucleophilic ( Michael ) addition to ( Ph2P)2C=CH2 when chelated to dimethylplatinum(II) , Di( o-tolyl) platinum(II) , or iodo(trimethyl)-platinum(IV). Crystal structure of [PtMe2I {PPh2CH(PPh2)CH2NHCH2Ph} ].

Fatma .S.M .Hassan ,Bernard L. Shaw ,and Mark. Thoronton-Pett, J.Chem. ,Soc. ,Dalton Trans.1998,3011.

7. Investigation of complexes of diphenyl phosphine derivatives by thermal and other physicochemical methods of analyses.

M.A.Zayed, Abd EI-Salam A.Arifien and F.S.M.Hassan, J.Thermal Analysis and Calorimetry , vol. 55 (1999), 205 -212.

8. Diphosphine Compounds: Part 1. Novel Biologically active carbon diphosphine and their complexes [M(CO)4{(Ph2P)(CHn)nPPh2] and [CuCl2 {(Ph2P)(CHn)nPPh2] ( M=Cr, Mo, W. ,n= 1,2 ) .

Ibrahim M.M.Awad , Fatma .S.M .Hassan ,Adila E.Mohamed , Ahmed F. Abd EI-Salam . Phosphorus, sulphur, and silicon, 179: 1-16 (2004).

Keyword: Functionalized disphosphine, Nucleophilic addition, Bimetallic Systems.